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class="ArticleTitle"> <h1><a href="http:///feiqichulishebeizhanshi/cuihuaranshaoshebei.html" target="_blank">催化燃燒</a>設(shè)備催化劑介紹</h1> </div> <div id="ekxdb5d6rf" class="ArticleMessage"><span>發(fā)布時間：2022-04-18 07:13</span><span>人氣：<i id="hits"><s id="rrzJsIdViewCount" style="display: inline;color:inherit;text-decoration:none;"><script type="text/javascript" src="/view/count.asp?t=article&id=191" async></script></s></i></span></div> <div class="ekxdb5d6rf" id="article" class="ArticleTencont"> <p> <p> <a href="http:///feiqichulishebeizhanshi/cuihuaranshaoshebei.html" target="_blank"><strong><a href="http:///feiqichulishebeizhanshi/cuihuaranshaoshebei.html" target="_blank">催化燃燒</a></strong></a>是借助催化劑在相對低溫下(200～350℃)下，將脫附設(shè)備中的有機氣體在引風(fēng)機的吸引下，廢氣送入<a href="http:///feiqichulishebeizhanshi/cuihuaranshaoshebei.html" target="_blank">催化燃燒</a>裝置，有機廢氣首先通過除塵阻火器系統(tǒng)，然后進入換熱器，再送入到加熱室，通過加熱裝置，使有機氣體達到燃燒反應(yīng)溫度，再通過催化劑床的作用，使有機氣體分解成二氧化碳和水，高溫潔凈氣體再進入換熱器與低溫脫附氣體進行熱交換，使脫附氣體溫度升高達到脫附所需要的反應(yīng)溫度。脫附氣體經(jīng)過催化燃燒后去除率達到97%以上。催化燃燒有著能耗少，操作簡便，安全，凈化效率高的優(yōu)點，在有機廢氣處理，特別是回收價值不大的有機廢氣凈化方面，諸如化工，噴漆、絕緣材料、漆包線、涂料生產(chǎn)等行業(yè)應(yīng)用較廣。催化燃燒設(shè)備中，催化劑是很重要的因素，催化劑中貴金屬的含量直接影響催化燃燒的效率，下面佑泰環(huán)保小編為您介紹一下催化燃燒系統(tǒng)中催化劑的相關(guān)知識。</p><p><img src="/storage/images/20220407/6f859e65505af077322f655f99c59791.jpg"/></p><p style="text-align: center;"><span style="font-size: 14px; color: rgb(30, 159, 255);"><a href="http:///feiqichulishebeizhanshi/cuihuaranshaoshebei.html" target="_blank">催化燃燒</a>一體機</span></p><p> 一、<a href="http:///feiqichulishebeizhanshi/cuihuaranshaoshebei.html" target="_blank">催化燃燒</a>系統(tǒng)催化劑：</p><p> (1)催化劑定義催化劑是一種能提高化學(xué)反應(yīng)速率，控制反應(yīng)方向，在反應(yīng)前后本身的化學(xué)性質(zhì)不發(fā)生改變的物質(zhì)。</p><p> (2)催化劑本身在一個化學(xué)反應(yīng)過程中，催化劑的加入并不能改變原有的化學(xué)平衡，所改變的僅是化學(xué)反應(yīng)的速度，而在反應(yīng)前后，催化劑本身的性質(zhì)并不發(fā)生變化，比如<a href="http:///feiqichulishebeizhanshi/cuihuaranshaoshebei.html" target="_blank">催化燃燒</a>設(shè)備之中所用的催化劑，光氧催化設(shè)備中所用的二氧化鈦催化板都是這樣。您肯定想知道催化劑是怎樣加速了反應(yīng)速度的呢？既然反應(yīng)前后催化劑不發(fā)生變化，那么催化劑到底參加了反應(yīng)沒有?實際上，催化劑本身參加了反應(yīng)，正是由于它的參加，使反應(yīng)改變了原有的途徑，使反應(yīng)的活化能降低，從而加速了反應(yīng)速度。例如反應(yīng)A+B→C是通過中間活性結(jié)合物(AB)過渡而成的，即：</p><p> A+B→[AB]→C</p><p> 其反應(yīng)速度較慢。當(dāng)加入催化劑K后，反應(yīng)從一條很容易進行的途徑實現(xiàn)：</p><p> A+B+2K→[AK]+[BK]→[CK]+K→C+2K</p><p> 加入催化劑后，反應(yīng)過程中間不再需要[AB]向C的過渡，從而加快了反應(yīng)速度，但是催化劑并未改變性質(zhì)。</p><p><img src="/storage/images/20211029/1-201209204935443.jpg"/></p><p style="text-align: center;"><span style="font-size: 14px; color: rgb(30, 159, 255);"><a href="http:///feiqichulishebeizhanshi/cuihuaranshaoshebei.html" target="_blank">催化燃燒</a>系統(tǒng)催化劑</span></p><p> 二、<a href="http:///feiqichulishebeizhanshi/cuihuaranshaoshebei.html" target="_blank">催化燃燒</a>催化劑構(gòu)成</p><p> 有機物<a href="http:///feiqichulishebeizhanshi/cuihuaranshaoshebei.html" target="_blank">催化燃燒</a>的催化劑分為貴金屬(以鉑、鈀為主)和賤金屬催化劑。貴金屬為活性組分的催化劑分為全金屬催化劑和以氧化鋁為載體的催化劑。全金屬催化劑是以鎳或鎳鉻合金為載體，將載體做成帶、片、丸、絲等形狀，采用化學(xué)鍍或電鍍的方法，將鉑、鈀等貴金屬沉積其上，然后做成便于裝卸的催化劑構(gòu)件。由氧化鋁作載體的貴金屬催化劑，一般是以陶瓷結(jié)構(gòu)作為支架，在陶瓷結(jié)構(gòu)上涂覆一層僅有0．的α-氧化鋁薄層，而活性組分鉑、鈀就以微晶狀態(tài)沉積或分散在多孔的氧化鋁薄層中。</p><p><img src="/storage/images/20220408/a0949877aa5b6fafb336658d31327272.jpg"/></p><p> 三、催化劑中毒與老化</p><p> 3.1、在催化劑使用過程中，由于體系中存在少量的雜質(zhì)，可使催化劑的活性和選擇性減小或者消失，這種現(xiàn)象叫催化劑中毒。這些能使催化劑中毒的物質(zhì)稱之為催化劑毒物，這些毒物在反應(yīng)過程中或強吸附在活性中心上，或與活性中心起化學(xué)作用而變?yōu)閯e的物質(zhì)，使活性中心失活。毒物通常是反應(yīng)原料中帶來的雜質(zhì)，或者是催化劑本身的某些雜質(zhì)，另外，反應(yīng)產(chǎn)物或副產(chǎn)物本身也可能對催化劑毒化，一般所指的是硫化物如、硫氧化碳、RSH等及含氧化合物如、CO2、O2以及含磷、砷、鹵素化合物、重金屬化合物等。</p><p> 毒物不單單是對催化劑來說的，而且還針對這個催化劑所催化的反應(yīng)，也就是說，對某一催化劑，只有聯(lián)系到它所催化的反應(yīng)時，才能清楚什么物質(zhì)是毒物。即使同一種催化劑，一種物質(zhì)可能毒化某一反應(yīng)而不影響另一反應(yīng)。</p><p> 3.2、按毒物與催化劑表面作用的程度可分為暫時性中毒和***性中毒。暫時性中毒亦稱可逆中毒，催化劑表面所吸附的毒物可用解吸的辦法驅(qū)逐，使催化劑恢復(fù)活性，然而這種可再生性一般也不能使催化劑恢復(fù)到中毒前的水平。***性中毒稱不可逆中毒，這時，毒物與催化劑活性中心生成了結(jié)合力很強的物質(zhì)，不能用一般方法將它去除或根本無法去除。</p><p><img src="/storage/images/20220408/efd672f0e3e052bab8960e3965b4c65c.jpg"/></p><p> 3.3、催化劑的老化主要是由于熱穩(wěn)定性與機械穩(wěn)定性決定的，例如低熔點活性組分的流失或升華，會大大降低催化劑的活性。催化劑的工作溫度對催化劑的老化影響很大，溫度選擇和控制不好，會使催化劑半熔或燒結(jié)，從而導(dǎo)致催化劑表面積的下降而降低活性。另外，內(nèi)部雜質(zhì)向表面的遷移，冷熱應(yīng)力交替所造成的機械性粉末被氣流帶走。所有這些，都會加速催化劑的老化，而其中***主要的是溫度的影響，工作溫度越高，老化速度越快。因此，在催化劑的活性溫度范圍內(nèi)選擇合適的反應(yīng)溫度將有助于延長催化劑的壽命。但是，過低的反應(yīng)溫度也是不可取的，會降低反應(yīng)速率。</p><p> 3.4、為了提高催化劑的熱穩(wěn)定性，常常選擇合適的耐高溫的載體來提高活性組分的分散度，可防止其顆粒變大而燒結(jié)，例如以純銅作催化劑時，在℃即失去活性，但如果采用共沉積法將Cu載于載體上，就能在較高的溫度下保持其活性。</p><p><br/></p></p> </div> <div id="ekxdb5d6rf" class="clear"></div> <div id="ekxdb5d6rf" class="reLink clearfix"> <div id="ekxdb5d6rf" class="prevLink"> <a href="/qishuifenliji/feiqichulishebei/190.html">上一篇：工業(yè)廢氣凈化簡介</a> </div> <div id="ekxdb5d6rf" class="nextLink"> <a 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