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id="article" class="ArticleTencont"> <p> <p>　　前言：<strong>電鍍廠廢氣</strong>產(chǎn)生的源頭是酸堿浸泡時(shí)揮發(fā)的酸霧和堿性氣體，廢氣腐蝕性較強(qiáng)，對人體危害很大。同時(shí)生產(chǎn)車間還有各種工藝揮發(fā)的無機(jī)廢氣及少量的VOC.常見的電鍍廢氣多為硝酸、鹽酸、硫酸、絡(luò)酸、氯于氰化物廢氣等，吸入濃度不等的酸堿賭氣會引起眼以及上呼吸道粘膜疾癥，出現(xiàn)流淚或者咳嗽等癥狀，嚴(yán)重時(shí)毒氣引入下呼吸道，導(dǎo)致肺水腫病態(tài)。氰化物毒性更佳的劇烈，慢性中毒可出現(xiàn)惡心流涎，意識喪失，0.2g即可奪人生命，引起重視和警惕。電鍍工業(yè)廢氣處理設(shè)備一般會釋放硝酸、硫酸、氫氟酸等氣體，處理用酸洗塔，將氣體抽到塔體內(nèi)進(jìn)行中和處理，然后經(jīng)抽風(fēng)機(jī)抽出都達(dá)標(biāo)排放。</p><p><img src="/storage/images/20220407/af36ef16dd5a3dc022aef50955b07a5b.jpg"/></p><p><strong>　　一、電鍍車間廢氣處理方法：</strong></p><p><br/></p><p>　　電鍍車間廢氣處理方案一：</p><p><br/></p><p>　　由吸風(fēng)罩、吸風(fēng)管收集通過引風(fēng)機(jī)鼓入凈化塔內(nèi)由下向上流動，通過一級噴淋的吸收液接觸反應(yīng)，吸收不有效后的廢氣繼續(xù)向上流動至三級噴淋的吸收液繼續(xù)接觸反應(yīng)。使氣液兩相充分接觸，經(jīng)處理后的凈化廢氣排放至15m高空。</p><p><br/></p><p>　　電鍍車間廢氣處理方案二：</p><p><br/></p><p>　　廢氣源→吸收塔(吸收掉電鍍槽中揮發(fā)出來的酸霧，為光催化提供優(yōu)良的運(yùn)行環(huán)境。酸霧廢氣，由吸風(fēng)罩、吸風(fēng)管收集通過引風(fēng)機(jī)鼓入凈化塔內(nèi)由下向上流動，通過一級噴淋的吸收液接觸反應(yīng)，吸收不有效后的廢氣繼續(xù)向上流動至三級噴淋的吸收液繼續(xù)接觸反應(yīng)。使氣液兩相充分接觸，)→光催化氧化處理設(shè)備(破壞廢氣分子結(jié)構(gòu)，轉(zhuǎn)化為無害物質(zhì))→高壓風(fēng)機(jī)(高壓的吸力作用下將風(fēng)抽出車間)→煙囪高空排放(也可低空排放)。</p><p><img src="/storage/images/20220409/adc8f4a737d1f17d0124b43ff779387e.jpg"/></p><p>　　電鍍車間廢氣處理方案三：</p><p><br/></p><p>　　廢氣源（車間收集好的）→吸收塔(吸收掉無機(jī)廢氣為等離子處理設(shè)備的運(yùn)行環(huán)境)→等離子處理設(shè)備(破壞分子結(jié)構(gòu)，生成無害物質(zhì))→高壓風(fēng)機(jī)(高壓的吸力作用下持續(xù)將廢氣抽出車間)→吸收塔(吸收小分子碎片，便于檢測達(dá)標(biāo))→煙囪高空排放(也可低空排放)。</p><p><br/></p><p>　<strong>　二、電鍍廠廢氣治理案例：</strong></p><p><br/></p><p>　　某電鍍廠生產(chǎn)類型以電鍍?yōu)橹?。在生產(chǎn)的過程中會產(chǎn)生大量的有害廢氣。電鍍生產(chǎn)工序較多，主要有除油、粗化、活化、鍍金、堿性鍍銅、鍍鎳、鍍錫等。電鍍生產(chǎn)過程中也會有大量的酸堿廢氣排出，濃度大、味道重。電鍍廢氣主要有以下二大類：是堿性氣體，主要來自于堿性除油等工序，成分主要是NaOH氣體等；第二類為，主要來源于堿銅缸的堿性含氰鍍銅，成分主要?dú)涞?。這些氣體如果不經(jīng)過處理直接排放的話，會對周圍環(huán)境及居民身體健康造成重大傷害。該廠房一層車間有鍍金鍍鎳流水線4條，主要產(chǎn)生含氰廢氣；二層車間鍍金、鍍鎳、鍍錫連續(xù)鍍流水線各2條，主要產(chǎn)生含氰廢氣及堿性氣體。</p><p><img src="/storage/images/20211101/e360927cddfd14d976d10fa392747eb7.jpg" width="745" height="559" border="0" vspace="0" title="噴淋塔" alt="噴淋塔" style="width: 745px; height: 559px;"/></p><p>　<strong>　1、處理工藝的選擇</strong></p><p><br/></p><p>　　電鍍廢氣處理的方法很多，其中以濕式洗滌法為應(yīng)用泛，效果良好。</p><p><br/></p><p>　　(1)濕式洗滌技術(shù)的原理如下。</p><p><br/></p><p>　?、儆捎谙礈煅b置中形成的大量水霧和水膜與吸入的氣體接觸，污染物顆粒撞擊在液滴表面而粘附在其上，增大了粒子體積，從而能有效地從氣流中分離出來。同時(shí)廢氣中所含的酸性氣體也在與水相的充分接觸中溶解在水中與堿性水霧結(jié)合形成中性鹽被分離出來。</p><p><br/></p><p>　?、跉饬髟谙到y(tǒng)中增濕，污染物相互凝聚能力加強(qiáng)。</p><p><br/></p><p>　　③氣流的湍流流動使污染的擴(kuò)散作用加強(qiáng)，易被液體粘附。</p><p><br/></p><p>　?、芟礈煳廴疚镏蟮乃茄h(huán)使用的，在循環(huán)過程中，必須加以適量的沉淀劑，并對產(chǎn)生的沉淀進(jìn)行分離，不要使過多的沉淀物反復(fù)加入循環(huán)，以免產(chǎn)生堵塞。</p><p><br/></p><p>　　根據(jù)本工程實(shí)際情況，單套處理系統(tǒng)風(fēng)量在35000~40000m3/h左右，風(fēng)量屬于中等類型，本工程擬采用性價(jià)比高的填料噴淋塔。</p><p><img src="/storage/images/20211101/019f4db037145a675ccd7d67a59945d8.jpg" width="745" height="553" border="0" vspace="0" title="電鍍廠廢氣處理" alt="電鍍廠廢氣處理" style="width: 745px; height: 553px;"/></p><p><strong>　　2、吸收液的選擇</strong></p><p><br/></p><p>　　（1）堿性廢氣和含氰廢氣：采用硫酸亞鐵溶液吸收。采用硫酸亞鐵水溶液作為吸收液時(shí)，PH保持在弱酸狀態(tài)，可以使凈化效率達(dá)到90%以上。故將含氰廢氣與NaOH廢氣一并處理。</p><p><br/></p><p><strong>　　3、工藝流程說明</strong></p><p><br/></p><p>　　廢氣處理設(shè)備的工作原理是將氣體中的污染物質(zhì)分離出來，轉(zhuǎn)化為無害物質(zhì)，以達(dá)到凈化氣體的的目的。它屬于微分接觸逆流式，塔體內(nèi)的填料是氣液雨相接觸的基本構(gòu)件。它能提供足夠大的表面積，對氣液流動又不致造成過大的阻力。吸收劑是處理廢氣的主要媒體，它的性質(zhì)和濃度是根據(jù)廢氣的性質(zhì)來選配。廢氣由風(fēng)管吸入，自下而上穿過填料層；循環(huán)吸收劑由塔頂通過霧化液體分布器，形成的水霧勻地噴淋到填料層中，沿著填料層表面向下流動，進(jìn)入循環(huán)水箱。由于上升氣流和下降霧化吸收劑在填料中不斷接觸，上升氣體中流質(zhì)的濃度愈來愈低，凈化器排出少量沒被吸附、吸收的有害物質(zhì)及粉塵再經(jīng)活性炭過濾、吸附，經(jīng)<strong><a href="http:///feiqichulishebeizhanshi/penlinta/huoxingtanxifuxiang/99.html" target="_blank">活性炭吸附箱</a></strong>后潔凈氣體達(dá)標(biāo)排放。</p><p><img src="/storage/images/20220408/a0949877aa5b6fafb336658d31327272.jpg"/></p><p><img src="/storage/images/20220408/efd672f0e3e052bab8960e3965b4c65c.jpg"/>　　</p></p> </div> <div id="mmoy8ssk" class="clear"></div> <div id="mmoy8ssk" class="reLink 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